HPLC Column, RP Phenyl Hexyl, 3um, 2.1mm ID x 150mm Length, 100A. Cogent Brand. 1 EA.

Additional Information:

Cogent RP Phenyl Hexyl™ is a reversed-phase HPLC stationary phase designed to provide enhanced aromatic selectivity through strong π-π interactions while maintaining hydrophobic retention characteristics. Manufactured using a six-carbon linker with a terminal phenyl ring bonded to ultra-high purity silica and fully double end capped, this stationary phase differs from traditional Phenyl phases by positioning the aromatic functionality farther from the silica surface. This increased distance reduces silanol influence and often enhances aromatic interactions, making the phase especially useful for compounds containing benzene rings and other aromatic structures. It is commonly used as an alternative in USP methods that specify L11 chemistry or Phenyl Hexyl phases.

68339-15P-2 is an HPLC column packed with 3 µm RP Phenyl Hexyl™ particles featuring a 100 Å pore size in a 2.1 mm ID x 150 mm format. This narrow-bore configuration combines high chromatographic resolution with reduced solvent consumption and compatibility with LC-MS instrumentation. The 150 mm length provides increased peak capacity and resolving power compared to shorter column formats, while the 3 µm particles provide greater efficiency and sharper peaks than comparable 5 µm columns. Typical operating flow rates are approximately 0.2–0.3 mL/min. Standard HPLC systems used with 2.1 mm ID columns must be capable of precise and reproducible low-flow operation.

This column is especially useful for the separation of aromatic compounds with moderate hydrophobicity, where the extended C6 linker can provide selectivity differences compared to traditional Phenyl phases. Typical applications include positional isomers, tocopherols, flavonoids, polynuclear aromatic hydrocarbons, nitro-aromatic compounds, active pharmaceutical ingredients (APIs), natural products, and related compounds. The 2.1 mm ID format is well suited for LC-MS methods requiring enhanced aromatic selectivity, excellent sensitivity, and low solvent consumption. For maximizing aromatic π-π interactions, methanol is often preferred over acetonitrile as the organic modifier.

Key Benefits

  • RP Phenyl Hexyl™ stationary phase

  • USP L11 equivalent selectivity

  • Fully double end capped

  • Six-carbon linker with terminal phenyl functionality

  • Ultra-high purity silica support

  • Enhanced π-π interactions

  • Improved aromatic compound selectivity

  • 3 µm particle size

  • Greater efficiency than 5 µm columns

  • Compatible with LC-MS applications

Typical Applications

  • USP L11 methods

  • LC-MS methods

  • Aromatic compound analysis

  • Positional isomer separations

  • Tocopherol analysis

  • Flavonoid analysis

  • Polynuclear aromatic hydrocarbon analysis

  • Nitro-aromatic compound analysis

  • Active pharmaceutical ingredient (API) analysis

  • Natural product analysis

Specifications

  • Product Type: HPLC Column

  • Stationary Phase: RP Phenyl Hexyl™

  • USP Classification: L11

  • Chromatography Mode: Reversed Phase

  • Bonded Phase: Phenyl Hexyl

  • Endcapping: Fully Double End Capped

  • Particle Size: 3 µm

  • Pore Size: 100 Å

  • Column Dimensions: 2.1 mm ID x 150 mm

  • Length: 150 mm

  • Typical Flow Rate: 0.2–0.3 mL/min

  • Brand: Cogent

Important Notes

  • Designed for aromatic compounds and compounds containing benzene rings

  • The six-carbon linker positions the phenyl group farther from the silica surface, enhancing aromatic interactions

  • Provides selectivity distinct from traditional Phenyl phases

  • Suitable for reversed-phase HPLC and LC-MS applications

  • The 2.1 mm ID format is commonly used for LC-MS methods

  • Standard HPLC systems must be capable of reliable operation at approximately 0.2–0.3 mL/min

  • Detector flow cells should be optimized for low-volume, narrow-bore chromatography

  • The 150 mm length provides greater resolution and peak capacity than shorter column formats

  • 3 µm particles provide higher efficiency and sharper peaks than comparable 5 µm columns

  • Methanol is often preferred over acetonitrile when optimizing π-π interactions


 

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